The effect of PA66 nanofibrous interlayers on mode II delamination behavior of filament-wound CFRP laminates at room and cryogenic temperatures

Official URL: https://dx.doi.org/10.1007/s10443-025-10353-1

This work aims to assess the potential of commercially available PA 6,6 nanofibrous mats when incorporated to large scale filament winding process. The conventional wet winding process was employed on a specially designed flat mandrel to manufacture uni-directional composite laminates. A49-12 K carbon fibers and cryogenic-compatible CTD 7.1 epoxy resin was employed. The winding process was temporarily paused at the mid-plane thickness to introduce a pre-crack using a 12 μm non-adherent film and to place PA66 nanofibers with an aerial weight of 3 g/m². The winding process then resumed. Laminate curing was performed in an autoclave oven for 3 h at 80oC under nitrogen environment. Flat wound laminates were then cut into end notched flexure (ENF) test samples in accordance with ASTM D7905/D7905M-19. ENF tests were performed at room temperature (RT) and cryogenic conditions in a liquid nitrogen bath. Test results suggested that mode II strain energy (GIIc) of interlayered laminates were 35% higher than the one of neat laminates when tested at room temperature. On the contrary, addition of polymeric nanofibrous interlayers reduced GIIc by 40% in cryogenic conditions. Fractographic analysis suggested that the improvement at RT was primarily due to (i) toughening at the resin rich pockets inherent by the tow-undulation effect in wet winding (ii) crack deflection in irregular tow-tow interfaces. The reduction in GIIc was attributed to synchrony of several factors, namely dominance of fiber/matrix debonding due to thermal contraction at fiber/resin interfaces, elevated brittleness of the polymeric nanofibers and pre-mature cracking due to nanofiber/resin debonding.