Amdouni, Wafa and Otoničar, Mojca and Alamarguy, David and Erdem, Emre and Gemeiner, Pascale and Mazaleyrat, Frédéric and Maghraoui-Meherzi, Hager and Kreisel, Jens and Glinsek, Sebastjan and Dkhil, Brahim (2024) Enhancement of the piezocatalytic response of la-doped BiFeO3 nanoparticles by defects synergy. Small, 20 (50). ISSN 1613-6810 (Print) 1613-6829 (Online)
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Official URL: https://dx.doi.org/10.1002/smll.202406425
Abstract
Because of their intrinsic polarization and related properties, ferroelectrics attract significant attention to address energy transformation and environmental protection. Here, by using trivalent-ion-lanthanum doping of BiFeO3 nanoparticles (NPs), it is shown that defects and piezoelectric potential are synergized to achieve a high piezocatalytic effect for decomposing the model Rhodamine B (RhB) pollutant, reaching a record-high piezocatalytic rate of 21 360 L mol−1 min−1 (i.e., 100% RhB degradation within 20 min) that exceeds most state-of-the art ferroelectrics. The piezocatalytic Bi0.99La0.01FeO3 NPs are also demonstrated to be versatile toward various pharmaceutical pollutants with over 90% removal efficiency, making them extremely efficient piezocatalysts for water purification. It is also shown that 1% La-doping introduces oxygen vacancies and Fe2+ defects. It is thus suggested that oxygen vacancies act as both active sites and charge providers, permitting more surface adsorption sites for the piezocatalysis process, and additional charges and better energy transfer between the NPs and surrounding molecules. Furthermore, the oxygen vacancies are proposed to couple to Fe2+ to form defect dipoles, which in turn introduces an internal field, resulting in more efficient charge de-trapping and separation when added to the piezopotential. This synergistic mechanism is believed to provide a new perspective for designing future piezocatalysts with high performance.
Item Type: | Article |
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Uncontrolled Keywords: | BiFeO3; defect dipoles; ferroelectric; oxygen vacancy; piezocatalysis |
Divisions: | Center of Excellence on Nano Diagnostics Faculty of Engineering and Natural Sciences |
Depositing User: | Emre Erdem |
Date Deposited: | 16 Dec 2024 12:36 |
Last Modified: | 16 Dec 2024 12:36 |
URI: | https://research.sabanciuniv.edu/id/eprint/50499 |