Assessment of the effect of electrophoretic deposition parameters on hydrogen storage performance of graphene oxide layer applied on nickel foam

Official URL: https://dx.doi.org/10.1016/j.ijhydene.2021.10.158

In this study, the hydrogen storage capacity of the graphene oxide layer was studied electrochemically. The graphene oxide was synthesized by modified Hummers' method and applied on the nickel foam by electrophoretic deposition (EPD) method at different potentials (20 and 60 V) and times (20 and 60 min) to determine the effect of applied potential and time of deposition on the hydrogen adsorption performance. The hydrogen adsorption tests including charge-discharge test, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV) were conducted in 6 M KOH solution and at room temperature. Based on the achieved CV curves, the graphene oxide (GO) layer achieved at 60 V within 20 min has a higher electrochemical hydrogen adsorption capability compared to other obtained samples. The calculated hydrogen storage capacity is obtained 50.9 mA. h. g−1. The rosette flower like morphology of the obtained GO layers at optimum condition, has an impressive effect on the improving electrochemical hydrogen adsorption based on morphology study by field emission scanning electron microscopy.