Oxidative fluorination of Cu/ZnO methanol catalysts

Dybbert, Valentin and Fehr, Samuel Matthias and Klein, Florian and Schaadt, Achim and Hoffmann, Anke and Frei, Elias and Erdem, Emre and Ludwig, Thilo and Hillebrecht, Harald and Krossing, Ingo (2019) Oxidative fluorination of Cu/ZnO methanol catalysts. Angewandte Chemie (International Edition) . ISSN 1433-7851 (Print) 1521-3773 (Online) Published Online First http://dx.doi.org/10.1002/anie.201811267

[thumbnail of Dybbert_et_al-2019-Angewandte_Chemie_International_Edition.pdf] PDF
Dybbert_et_al-2019-Angewandte_Chemie_International_Edition.pdf
Restricted to Registered users only

Download (958kB) | Request a copy

Abstract

The influence of a mild difluorine treatment on Cu/ZnO precatalysts for methanol synthesis was investigated. It led to the incorporation of 1.2…1.3±0.1 wt % fluoride into the material. Fluorination considerably increased the amount of ZnOx related defect sites on the catalysts and significantly increased the space‐time yields. Although the apparent activation energy E(A,app) for methanol formation from CO2 and H2 was almost unchanged, the E(A,app) for the reverse water‐gas shift (rWGS) reaction increased considerably. Overall, fluorination led to a significant gain in methanol selectivity and productivity. Apparently, also the quantity of active sites increased.
Item Type: Article
Subjects: Q Science > Q Science (General)
Q Science > QD Chemistry
Q Science > QC Physics
Divisions: Sabancı University Nanotechnology Research and Application Center
Faculty of Engineering and Natural Sciences > Academic programs > Materials Science & Eng.
Faculty of Engineering and Natural Sciences
Depositing User: Emre Erdem
Date Deposited: 24 Aug 2019 23:28
Last Modified: 26 Apr 2022 10:10
URI: https://research.sabanciuniv.edu/id/eprint/38584

Actions (login required)

View Item
View Item