Through the challenging synthesis of tetraphenylporphyrin derivatives bearing nitroxide moieties
Önal, Emel and Fidan, İsmail and Luneau, Dominique and Hirel Aslan, Catherine (2019) Through the challenging synthesis of tetraphenylporphyrin derivatives bearing nitroxide moieties. Journal of Porphyrins and Phthalocyanines, 23 (4-5). pp. 584-588. ISSN 1088-4246 (Print) 1099-1409 (Online)
Official URL: http://dx.doi.org/10.1142/S1088424619500500
Tetraphenylporphyrin derivatives a synthetic heterocycles with convenient preparation and a richness of properties which make them attractive in broad fields such as energy, life and materials sciences. Thus, in the quest for new radical architectures, tetraphenylporphyrins are prime candidates. To this end, we designed free-base tetraphenylporphyrins bearing nitronyl and imino nitroxide moieties covalently bonded to the para-position of the meso-phenyl substituent. Their detailed synthesis and characterization arc reported here.
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