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Nonisocyanate based polyurethane/silica nanocomposites and their coating performance

Türünç, Oğuz and Kayaman-Apohan, Nilhan and Kahraman, M. Vezir and Menceloğlu, Yusuf Z. and Güngör, Atilla (2008) Nonisocyanate based polyurethane/silica nanocomposites and their coating performance. Journal of Sol-Gel Science and Technology, 47 (3). pp. 290-299. ISSN 0928-0707 (Print) 1573-4846 (Online)

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Official URL: http://dx.doi.org/10.1007/s10971-008-1786-0

Abstract

A series of silica nano-particles with different size were prepared by sol–gel technique, then surface modification by using cyclic carbonate functional organoalkoxysilane (CPS) was performed. Various amounts of carbonated silica particles directly added into carbonated soybean oil (CSBO) and carbonated polypropylene glycol (CPPG) resin mixture to prepare polyurethane–silica nanocomposite coating compositions by nonisocyanate route using an aliphatic diamine as a curing agent. Cupping, gloss, impact, and taber abrasion tests were performed on aluminum panels coated with those nano-composite formulations and tensile tests, thermogravimetric and SEM analyses were conducted on the free films prepared from the same coating formulations. An increase in abrasion resistance of CSBO-CPPG resin combination with the addition of silica was observed. In addition, the maximum weight loss of CSBO-CPPG resin combination was shifted to higher temperatures with incorporation of silica nano-particles The positive effect of modified silica particles on thermal stability of CSBO-CPPG system could be explained in such a way that PPG chains are able to disperse particles in the medium throughout the interactions between ether linkages and silanol groups.

Item Type:Article
Uncontrolled Keywords:Silica - Nonisocyanate polyurethane - Nanocomposite - Cyclic carbonate
Subjects:T Technology > TP Chemical technology > TP1080 Polymers and polymer manufacture
ID Code:9626
Deposited By:Yusuf Z. Menceloğlu
Deposited On:26 Oct 2008 19:47
Last Modified:25 May 2011 14:09

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