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Non-isothermal kinetics of pyrolysis of Turkish petroleum pitches

Okyay Öner, Firuze and Yürüm, Alp and Yürüm, Yuda (2016) Non-isothermal kinetics of pyrolysis of Turkish petroleum pitches. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 38 (15). pp. 2197-2204. ISSN 1556-7036 (Print) 1556-7230 (Online)

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Official URL: http://dx.doi.org/10.1080/15567036.2015.1047067

Abstract

Non-isothermal thermogravimetric data of two Turkish petroleum pitches were used to evaluate kinetic parameters of pyrolysis reactions. The article reports the application of Ozawa-Flynn-Wall model to deal with non-isothermal TG data for the evaluation of the activation energy corresponding to the pyrolysis of two different petroleum pitches. Non-isothermal kinetic studies of pyrolysis of the pitches based on the TGA measurements at different heating rates resulted that average activation energy of pyrolysis of pitch B (213 kJ/mol) was higher than that of average activation energy of pitch A (186 kJ/mol). Reaction orders of pitch A and pitch B were calculated as 0.6 and 0.9, respectively.

Item Type:Article
Uncontrolled Keywords:Activation energy; non-isothermal kinetics; petroleum pitches; pyrolysis; thermogravimetry
Subjects:T Technology > TP Chemical technology > TP0155-156 Chemical engineering
T Technology > TP Chemical technology > TP0315-360 Fuel
ID Code:30008
Deposited By:Yuda Yürüm
Deposited On:10 Nov 2016 14:58
Last Modified:10 Nov 2016 14:58

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